PRINCIPLE OF THERMOCHROMISM

ChromaZone is a microencapsulated thermochromic pigment which changes from colour to colourless as the temperature rises. With decreasing temperature the colour returns. The pigment is encapsulated in aqueous conditions and the resultant pigment is in slurry form.

The capsules are individual droplets of chromogenic material with an impervious polymeric wall. The particle size is below 6 micron. The microcapsule wall can withstand most standard mixing and application procedures. If too much shear energy is used (e.g. bead mills) the microcapsules can be crushed, therefore, the ChromaZone and the thermochromic functionality will be destroyed.
 

Three components are enclosed in the microcapsule forming the thermochromic effect. Graphic 1 explains the principle of the reaction.

The reaction can be disrupted by several external influences such as high exposure to UV light, presence of polar solvents, very high temperatures or excessive shear.

Due to their chemical and physical properties the visible colour change of ChromaZone pigments occurs over a temperature range of approximately 5ºC and additionally shows a thermal hysteresis. This means that the colour starts disappearing before reaching the relevant response temperature and at the ensuing temperature decrease requires a significantly lower temperature to regain full colour strength. Graphic 2 shows the effect
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Graphic 1 CLICK ON IMAGE TO ENLARGE
 
Graphic 2
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